Physical organic chemistry refers to a discipline of organic chemistry that focuses on the relationship between chemical structures and reactivity, in particular, applying experimental tools of physical chemistry to the study of organic molecules. The text Physical Organic Chemistry applies the experimental tools of physical chemistry to the study of the structure of organic molecules and provides a theoretical framework that interprets how structure influences both mechanisms and rates of organic reactions. In first chapter, the surface chemistry and properties of aqueous atmospheric aerosols have been explored. A graph-theoretical approach to calculate vibrational energies of atomic and subatomic systems has been proposed in second chapter. In third chapter; quasicrystals, types, physical properties, surface science and potential applications of them have been discussed. Molecular structure and vibrational spectra of 2-ethylhexyl acrylate by density functional theory calculations have been discussed in fourth chapter. In fifth chapter; three-center four-, three-, and two electron systems based on carbon-, boron-, hydrogen-, and halogen exchange have been considered. Thermochemical parameters of tetramethylthiourea adducts of certain metal (II) bromides have been focused in sixth chapter. A molecular dynamics simulation study of two dipeptide based molecular micelles has been introduced in seventh chapter. Eighth chapter focuses on composition, stability and probable structure of a colorless organometallic complex. Inhibition mechanism of pitting corrosion of nickel in aqueous medium by some macrocyclic compounds has been presented in ninth chapter. A computational evaluation of bond order and charge distributions in isomeric aminotroponiminiums and their benzo-fused derivatives has been discussed in tenth chapter. In eleventh chapter, we develop a cyclic voltammetric procedure to obtain β-NiOOH or γ-NiOOH/β-NiOOH mixtures on Ni or Ni-Cr (80:20) alloy electrodes surfaces. In twelfth chapter, the kinetics and products of the reaction of cyclic monoimides with oxiranes in presence of triethylamine (TEA) as catalyst have been studied in order to establish the mechanism of the reaction. Thirteenth chapter focuses on inert gas-clustered systems and examines their stability as a result of interparticulate interaction. Fourteenth chapter describes in silico study on sulfated and non-sulfated carbohydrate chains from proteoglycans in cnidaria. Fifteenth chapter discusses on aminolysis of 1-(1-hydroxybenzotriazolyl)-2,4-dinitrobenzene and 2-(1-hydroxybenzotriazolyl)-5-nitropyridine. The aim of sixteenth chapter is to explore the conformational behavior of the LIGNOLs in aqueous solution adopting the TIP4P model. Analysis of phenacylester derivatives of fatty acids from human skin surface sebum by reversed-phase HPLC has been described in seventeenth chapter Eighteenth chapter focuses on synthesis and bioactivity of Luffarin I. Formylation of electron-rich aromatic rings mediated by dichloromethyl methyl ether and TiCl4 has been focused in nineteenth chapter. A greatly under-appreciated fundamental principle of physical organic chemistry has been proposed in last chapter.
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