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[日] 足立元成 、[加拿大] 洛克伍德 (Lockwood D.J.) 著 / 科学出版社 / 2007-04 / 精装
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自组织纳米材料
《自组织纳米材料(影印版)》包含了大量通过化学、仿生学途径并运用自组织机制合成纳米材料并产生不同尺度的组件的方法。过去的几十年里。纳米结构新颖的系统性能在自然科学的各个领域中得到广泛认可,新技术的不断发展吸引了各个领域的科学家投入到与之相关的研究中。要全面实现纳米科学与技术的巨大应用前景,面临的重要挑战就是寻找在原子尺度上调制排列结构的方法以及构造原子、介观、宏观各尺度层次的材料。《自组织纳米材料(影印版)》介绍了纳米结构自组装领域从基础理论到相关应用的大量令人鼓舞的最新进展,可供物理学、化学、生物学、工程和材料科学领域中科研人员和研究生参考。
Preface1、Self-AssembledSi1-xGexDotsandIslandsJean-MarcBaribeau,NelsonL.Rowell,andDavidJ.Lockwood1.1Introduction1.2Si1-xGexIslandGrowth1.2.1GrowthModesinHeteroepitaxy1.2.2Si1-xGexIslandGrowthandShapeEvolution1.2.3Si1-xGexIslandCompositionandStrainDistribution1.3StackedSi1-xGexIslands1.3.1DevelopmentofMorphologicalInstabilitiesinHeteroepitaxy1.3.2Synthesis,Structure,andVerticalCorrelation1.3.3VibrationalProperties1.3.4OpticalProperties1.4EngineeringofSi1-xGexIslands1.4.1InfluenceofSurfaceMorphology1.4.2InfluenceofAdsorbedSpecies1.5ApplicationsofSi1-xGexIslandsandDots1.5.1Photodetectors1.5.2OtherApplications1.6SummaryandFutureProspectsReferences2、SynthesisofTitaniaNanoerystals:ApplicationforDye-SensitizedSolarCellsMotonariAdachi,YusukeMurata,FuminWang,andJintingJiu2.1FormationofTitaniaNanocrystalsbySurfactant-AssistedMethods2.1.1Introduction:HowtoControlMorphologyandFunctionalizeCeramicMaterials2.1.2FormationofNetworkStructureofSingleCrystallineTiO2Nanowiresbythe"OrientedAttachment"Mechanism2.1.3MorphologicalControlofAnataseNanocrystalsUsingDodecanediamineasaSurfactant2.2ApplicationofTiO2NetworkofSingle-CrystallineNanowiresforDye-SensitizedSolarCells2.2.1Introduction2.2.2HowtoMaketheDye-SensitizedSolarCells2.2.3CharacterizationoftheSolarCellsMadeofNetworkofSingle-CrystallineAnataseExposingMainlythe{101}Plane2.3SummaryReferences3、SoftSynthesisofInorganicNanorods,Nanowires,andNanotubesShu-HongYuandYi-TaiQian3.1Introduction3.2AnOverview:EmergingSyntheticRoutesfortheSynthesisofLow-DimensionalNanocrystals3.2.1"Hard"Approaches3.2.2"Soft"Approaches3.3SoftSynthesisofLow-DimensionalNanocrystals3.3.1Hydrothermal/SolvothermalProcesses3.3.2SynthesisofSemiconductorNanorods/NanowiresbySolution-Liquid-SolidMechanism3.3.3CappingAgents/Surfactant-AssistedSoftSynthesis3.3.4Bio-InspiredApproachforComplexSuperstructures3.3.5OrientedAttachmentGrowthMechanism3.4SummaryandOutlookReferences4、AssemblyofZeolitesandCrystallineMolecularSievesJenniferL.AnthonyandMarkE.Davis4.1Introduction4.2ThermodynamicsofSynthesisProcesses4.3KineticsofSynthesisProcesses4.4AssemblyProcesses4.4.1ProposedMechanismsforZeoliteAssembly4.4.2MetaMon-AssistedAssemblyProcesses4.5ComponentsofSynthesis4.5.1OrganicComponents4.5.2InorganicComponents4.6Chirality:CanaDesignerZeohteBeSynthesized4.7SummaryReferences5、MolecularImprintingbytheSurfaceSol-GelProcess:TemplatedNanoporousMetalOxideThinFilmsforMolecularRecognitionSeung-WooLeeandToyokiKunitake5.1Introduction5.2SurfaceSol-GelProcess5.2.1PreparationofAmorphousMetalOxideThinFilms5.2.2RichVarietyofOrganicComponentsinNanohybridLayers5.3MolecularImprintinginAmorphousMetalOxideFilms5.3.1IncorporationandRemovalofTemplates5.3.2StabilityandSelectivityofImprintedSites5.3.3NatureofImprintedSitesforGuestBinding5.3.4MultifunctionalNatureofImprintedCavity5.3.5VariedMolecularSelectivity5.4PracticalPotentials5.4.1RecognitionofBiologicalMolecules5.4.2ContrivanceforHighSensitivity5.4.3RecognitionofCoordinationGeometry5.4.4NanoporousThinFilmswithIon-ExchangeSites5.4.5DirectObservationofImprintedCavity-PhysicalCavityVersusTopologicalCavity5.5UnsolvedProblemsandFutureProspectsReferences6、Fabrication,Characterization,andApplicationsofTemplate-SynthesizedNanotubesandNanotubeMembranesPunitKohliandCharlesR.Martin6.1Introduction6.2Nomenclature6.3TemplateSynthesisofNanotubes6.4SilicaNanotubes6.4.1AttachingDifferentFunctionalGroupstotheInsideVersusOutsideSurfaces6.4.2NanotubesforChemicalandBioextractionandBiocatalysis:DemonstrationofPotentialDrugDetoxificationUsingNanotubes6.5TemplateSynthesisofNanoTestTubes6.6NanotubeMembranesforBioseparations6.6.1Antibody-FunctionalizedNanotubeMembranesforSelectiveEnantiomericSeparations6.6.2FunctionalizedNanotubeMembraneswith"Hairpin"-DNATransporterwithSingle-BaseMismatchSelectivity6.7ConicalNanotubes:MimickingArtificialIonChannel6.8ConclusionsReferences7、SynthesisandCharacterizationofCore-ShellStructuredMetalsTetsuYonezawa7.1Introduction7.2PreparationofCore-ShellBimetallicNanoparticles7.2.1PreparationProcedures7.2.2SuccessiveReductionoftheCorrespondingTwoMetalIons7.2.3SimultaneousReductionoftheCorrespondingTwoMetalIons7.2.4OtherSystems7.3CharacterizationofCore-ShellBimetallicNanoparticles7.3.1X-rayCharacterization7.3.2ElectronMicroscopicObservations7.3.3UV-visSpectroscopy7.3.4IRSpectroscopyofChemicalProbes7.4SummaryReferences8、CobaltNanocrystalsOrganizedinMesoseopieScaleMarie-PaulePileni8.1Introduction8.2Self-OrganizationofCobaltNanocrystals8.3CollectiveMagneticPropertiesofMesostructuresMadeofMagneticNanocrystals8.4ConclusionReferences9、SynthesisandApplicationsofHighlyOrderedAnodicPorousAluminaHidekiMasudaandKazuyukiNishio9.1Introduction9.2SynthesisofHighlyOrderedAnodicPorousAlumina9.2.1GrowthofAnodicPorousAluminaonAl9.2.2SynthesisofHighlyOrderedAnodicPorousAlumina9.2.3IdeallyOrderedAnodicPorousAluminabythePretexturingProcessUsingMolds9.3OrderedNanostructuresBasedonHighlyOrderedAnodicPorousAlumina9.3.1NanocompositeStructuresUsingHighlyOrderedAnodicPorousAlumina9.3.2NanofabricationUsingAnodicPorousAluminaMasks9.3.3Two-StepReplicationProcessforFunctionalNanoholeArrays9.3.4OrderedArrayofBiomoleculesUsingHighlyOrderedAnodicPorousAlumina9.4ConclusionsReferencesIndex
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