陶瓷新型胶态成型工艺

《陶瓷新型胶态成型工艺》系统、完整地介绍了清华大学黄勇科研组在过去20多年里在高性能陶瓷成型工艺领域取得的研究成果，同时，还论述了其他国家学者近年来在陶瓷成型领域所取得的进展。《陶瓷新型胶态成型工艺》内容分为7章，包括：基于凝胶体系的陶瓷胶态注射成型新工艺；陶瓷基片的凝胶流延工艺；无毒或低毒体系凝胶成型工艺；陶瓷制备过程中缺陷的产生、演化、遗传和控制：非氧化物陶瓷凝胶注模成型新工艺；胶态成型工艺的应用；胶态成型工艺新方法和新技术。

黄勇，男，清华大学教授，博士生导师。1937年出生于福建。1962年毕业于清华大学并留校工作；1959-1961年，在南京化工学院研修硅酸盐专业。曾先后在美国密歇根大学、麻省理工学院、瑞士联邦技术学院、澳大利亚Monash大学等担任访问学者或进行短期高访、讲学与合作研究。曾任清华大学材料科学与工程系主任、清华大学材料科学与工程研究院常务副院长、第六和第七届国家自然科学基金委员会学科评审组成员、S-863计划软课题专家组成员、国家“八五”科技攻关计划陶瓷发动机专家组成员等，现任中国硅酸盐学会常务理事和特种陶瓷分会理事长、《硅酸盐学报》主编等。

JinlongYang，Bornin1966，graduatedfromBeijingInstituteofTechnologyin1987，graduatedandgotthemasterdegreefromNorthUniversityofChina（NUC）in1990，gotthedoctordegreefromTsinghuaUniversityin1996.Hehadthepost-doctoralexperienceatDepartmentofMaterialsinSwissFederalInstituteofTechnology（ETH-Zurich）from1999to2000.HebecameafullprofessorinTsinghuaUniversityin2004，andhadthepositionofspecial-engagedprofessoranddirectoroflaboratoryofadvancedceramicsinNUCsince2006.Researchfieldsinclude：structuredceramics，ceramicmatrixcomposites，colloidalformingtechnologyofceramicsandlasergreenmachiningofceramics.Hehadwonsometophonors，includingthesecondclassprizeofNationalTechnologyInventionforaresearchprogrambyStateCouncilofChina，and"ScienceandTechnologyAdvancementPrize"forotherthreeprogramsawardedbytheMinistryofEducationandthegovernmentofBeijingrespectively.Hehasdeliveredmorethan100papers，andgot30statepatentsforinvention.

Chapter1AqueousColloidalInjectionMoldingofCeramicsBasedonGelation
1.1ColloidalInjectionMolding
1.1.1TheConceptofCIMC
1.1.2TheFlowchartofCIMC
1.1.3TheMachineofCIMC
1.2PressureInducedForming
1.2.1EffectofHydrostaticPressureonSolidification
1.2.2HomogeneityoftheGreenBodies
1.2.3ControllingtheInnerStressintheGreenBody
1.3StorageStabilityofCeramicSlurries
1.3.1TheImportanceofStorageStabilityofSlurry
1.3.2ChemicalStability
1.3.3InhibitorforSlurryStorage
1.4ToPrepareHighReliabilityCeramicPartswithComplexShapes：AqueousColloidalInjectionMolding
References

Chapter2Gel-Tape-CastingofCeramicSubstrates
2.1FundamentalPrincipleandProcessingofAqueousGel-Tape-Casting
2.1.1TapeCastingTypesandtheRawMaterials
2.1.2PolymerizationoftheMonomer
2.1.3InfluenceFactorsonPolymerizationoftheMonomer
2.1.4ProcessingoftheGel-Tape-Casting
2.2TheCharacteristicsofSlurriesUsedforAqueousGel-Tape-Casting
2.2.1ThePropertiesoftheAqueousCeramicSlurrieswithBinder
2.2.2TheInfluenceofDispersantsonStabilityandRheologyofAqueousCeramicSlurrieswithOrganicMonomer
2.2.3TheInfluenceofPlasticizeronPropertiesofAqueousCeramicSlurrywithOrganicMonomer
2.2.4TheInfluenceofpHonthePropertiesofSlurrieswithOrganicMonomer
2.2.5TheEffectofSurfactantonWettingandGreenTapeReleasing（Separating）
2.2.6FoamandPoreElimination
2.2.7SinteringofGreenTapePreparedbySlurry
2.3AqueousGel-Tape-CastingwithStyrene-AcrylicLatexBinder
2.3.1TheImportanceofBindersinGel-Tape-CastingProcess
2.3.2TheFormingFilmMechanismofLatexBinder
2.3.3RaheologicalPropertiesoftheAluminaSlurrieswithBinder
2.3.4ThePhysicalPropertiesandMicrostructureofGreenTapeswithLatexBinder
2.4AGel-Tape-CastingProcessBasedonGelationofSodiumAlginate
2.4.1WhyStudyonTapeCastingofSodiumAlginate
2.4.2ThePreparationofAqueousAluminaSuspensionswithSodiumAlginateandCalciumPhosphereTribasic
2.4.3ControloftheGelationofSodiumAlginate
2.4.4CharacterizationofGreenTapes
2.5TheSprayTriggerFast-CuringfortheGel-Tape-CastingProcess
2.5.1TheIdeaoftheSprayTriggerFast-Curing
2.5.2OutlineoftheNewProcess
2.6TheFeaturesandProspectsoftheAqueousTape-Casting
References

Chapter3GelationFormingProcessforLowToxicitySystem
3.1GelationFormingofCeramicSuspensionwithAgarose
3.1.1CharacteristicsofAgarose
3.1.2TheEffectofAgaroseContentsontheRheologyofAqueousCeramicSuspensions
3.1.3TheFormingCoursesoftheAqueousCeramicSuspensionswithAgarose
3.2AluminaCastingBasedonGelationofGelatine
3.2.1CharacteristicsofGelatine
3.2.2TheGelationProcessoftheCeramicSlurrywithGelatineSolution
3.2.3ThePreparationofGreenBodyUsingSlurrywithGelatineSolution
3.3ACastingFormingforCeramicsbyGelatineandEnzymeCatalysis
3.3.1ResearchBackground
3.3.2TheGelationMechanismofGelatineSolutionwithUreaunderEnzymeCatalysis
3.3.3TheRheologyandZetaPotentialofAluminaSuspensionContainingGelatineandUrea
3.3.4TheCoagulationFormingandMicrostructureofGreenBody
3.4TheAluminaFormingBasedonGelationofSodiumAlginate
3.4.1ResearchBackground
3.4.2TheGelationPrincipleofSodiumAlginate
3.4.3ThePreparationProcessofAluminaGreenBodiesandSamplesbySodiumAlginate
3.5TheGel-CastingofSiCBasedonGelationofSodiumAlginate
3.5.1IntroductionoftheResearch
3.5.2TheEffectofDispersantontheColloidalBehaviorsoftheSiCSuspension
3.5.3TheRheologicalPropertyofSiCSuspension
3.5.4TheSedimentationBehavioroftheSiCSuspension
3.5.5TheGelationPrincipleandProcessoftheAlginateSolution
3.5.6TheGelationoftheSiCSuspensionwithAlginate
3.6TheAluminaGel-CastingwithaLow-ToxicitySystemofHEMA
3.6.1TheAcademicIdeaandResearchProgram
3.6.2TheColloidalChemistryandRheologicalProperty
3.6.3TheBinderBurnoutandApplicationoftheNewSystem
3.7TheSynergisticLow-ToxicityGel-CastingSystembyUsingHEMAandPVP
3.7.1TheAcademicIdeaandResearchProgram
3.7.2ZetaPotentialsandRheologicalProperties
3.7.3TheActivationEnergyandSolidification
3.7.4TheGreenStrengthsandMicrostructures
3.7.5TheExfoliationEliminationEffectandAnalysisoftheInteractionbetweenPVPandHEMAMolecules
References

Chapter4Generation，Development，Inheritance，andControloftheDefectsduringtheTransformationfromSuspensiontoGreenBody
4.1TheRheologicalBehaviorsofAqueousCeramicSuspensions
4.1.1TheR.heologicalBehaviorsofAqueousAluminaSuspensions
4.1.2TheEffectofRheologicalPropertiesofSuspensiononMechanicalStrengthofCeramics
4.1.3TheEffectofSolidLoadingonColloidalForming
4.2TheGenerationandDevelopmentofDefects
4.2.1TheGenerationMechanismsofAgglomerationsinCeramicSuspensions
4.2.2TheInfluencesofIdleTimeonMicrostructuresandMechanicalPropertiesofGreenBodiesbyDirectCoagulationCasting
4.3TheEffectofIonicConductanceonPreparationofHighlyConcentratedSuspension
4.3.1TheAcademicIdeaandResearchProgram
4.3.2TheRelationshipBetweenIonConductivityConstantsandSolidLoading
4.4ControlofInnerStressinGreenBody
4.4.1Origin，TransformationandControlofInnerStressinGreenBody
4.4.2TheReleaseandControlofInnerStressesinCeramicGreenBody
4.5TheSuppressionofSurface-ExfoliationwiththeAdditionofOrganicAgents
4.5.1TheSuppressionofSurface-ExfoliationbyIntroducingPAMintoMonomerSysteminSuspension
4.5.2TheSuppressionofSurface-ExfoliationbyIntroducingPolyethyleneGlycolintoMonomerSysteminSuspension
4.5.3TheSuppressionofSurface-ExfoliationbyIntroducingPoly-vinylpyrrolidone（PVP）intoMonomerSysteminSuspension
References

Chapter5TheGel-CastingofNon-OxideCeramics
5.1TheEffectsofPowderSurfaceModificationonConcentratedSuspensionsPropertiesofSi3N4
5.1.1TheContributingFactorandEliminationofMacroporesinSi3N4GreenBodies
5.1.2TheEffectofForeignIonsonConcentratedSuspensionofSi3N4
5.1.3TheEffectofAcidCleaningandCalcinationsontheSuspensionPropertiesofSi3N4
5.1.4TheEffectofLiquidMediumandSurfaceGrouponDispersibilityofSi3N4Powder
5.2TheGel-CastingofSi3N4Ceramics
5.2.1ThePreparationofSi3N4CeramicswithSurface-CoatedSi3N4Powder
5.2.2ThePreparationofSi3N4CeramicswithSurface-OxidizedSi3N4Powder
……
Chapter6ApplicationofNewColloidalForming
Chapter7TheNewMethodsandTechniquesBasedonGel-Casting
Appendix
IndexofTerms
IndexofScholars
Postscript