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褚良银 著 / 浙江大学出版社 / 2011-06 / 精装
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中国科技进展丛书·智能膜材料与膜系统:从平板膜到微囊膜
Asemergingartificialbiomimeticmembranes,smartorintelligentmembranesthatareabletorespondtoenvironmentalstimuliareattractingever-increasinginterestfromvariousfields.Theirsurfacecharacteristicsand/orpermeationpropertiesincludinghydraulicpermeability(pressure-drivenconvectiveflowofsolvents)anddiffusionalpermeability(concentration-drivenmoleculardiffusionofsolutes)canbedramaticallycontrolledoradjustedself-regulativelyinresponsetosmallchemicaland/orphysicalstimuliintheirenvironments,suchastemperature,pH,ionicstrength,electricalfield,photoirradiation,glucoseconcentration,oxidoreductionand/orchemicalorbiologicalspecies.Suchenvironmentalstimuli-responsivesmartmembranescouldfindmyriadapplicationsinnumerousfieldsrangingfromcontrolleddrugdelivery,tochemicalseparation,towatertreatment,tobioseparation,tochemicalsensors,tochemicalvalves,totissueengineering,etc.Thedevelopmentofthesesmartorintelligentmembranesisofbothscientificandtechnologicalinterest.
1Introduction1.1AGlanceatMembranesandTheirDevelopments1.2EnvironmentalStimuli-ResponsiveGatingModelofBiomembranes1.3EnvironmentalStimuli-ResponsiveSmartMaterials1.3.1Thermo-ResponsiveSmartMaterials1.3.2pH-ResponsiveSmartMaterials1.3.3Glucose-ResponsiveSmartMaterials1.3.4Molecular-RecognizableSmartMaterials1.4Bio-InspiredDesignofEnvironmentalStimuli-ResponsiveSmartMembranes1.4.1SmartMembraneswithPorousSubstratesandStimuli-ResponsiveGates1.4.2SmartMembraneswithGraftedStimuli-ResponsiveSurfaces1.4.3Stimuli-ResponsiveSmartHydrogelMembranesReferences2Thermo-ResponsiveGatingMembranes:Design,MicrostructuresandPerformances2.1DesignofThermo-ResponsiveGatingMembranes2.2FormationandMicrostructuresofGraftedPNIPAMPolymersin发`Pore-FillingTypeThermo-ResponsiveGatingMembranes2.2.1Pore-FillingTypeThermo-ResponsiveGatingMembranesFabricatedbyPlasma-InducedGraftingPolymerization2.2.2Pore-FillingTypeThermo-ResponsiveGatingMembranesFabricatedbyAtom-TransferRadicalPolymerization2.3EffectoftheGraftingYieldonThermo-ResponsiveGatingCharacteristicsofPore-FillingTypePNIPAM-GraftedMembranes2.3.1SubstrateMembraneswithRegularStraightPoreMicrostructures2.3.2SubstrateMembraneswithIrregularPoreMicrostructures2.4EffectoftheLengthandDensityofGraftedChainsonThermo-ResponsiveGatingCharacteristicsofPNIPAM-GraftedGatingMembranes2.5GatingCharacteristicsofThermo-ResponsiveMembraneswithGraftedLinearandCrosslinkedPNIPAMGates2.6Thermo-ResponsiveWettabilityCharacteristicsofPNIPAM-GrafiedMembranes2.7Thermo-ResponsiveGatingMembraneswithControllableResponseTemperature2.8MembraneswithNegativelyThermo-ResponsiveGatingCharacteristicsReferences3SmartMicrocapsuleswithThermo-ResponsiveGatingMembranes3.1DesignofSmartMicrocapsuleswithThermo-ResponsiveGatingMembranes3.2FabricationandPerformanceofThermo-ResponsiveMicrocapsuleswithPorousMembraneandPNIPAMGates3.2.1FabricationofHollowMicrocapsuleswithPorousMembrane3.2.2GraftingPNIPAMGatesintheMembranePoresofMicrocapsules3.2.3Thermo-ResponsiveControlled-ReleaseCharacteristics3.3MonodispersedThermo-ResponsiveMicrocapsuleswithPorousMembraneandPNIPAMGates3.3.1PreparationofMonodispersedMicrocapsuleswithPorousMembrane3.3.2MonodispersedMicrocapsuleswithPorousMembraneandGraftedPNIPAMGates3.3.3Thermo-ResponsiveControlled-ReleaseCharacteristicsReferences4SmartMicrocapsuleswithThermo-ResponsiveHydrogelMembranes4.1Introduction4.2MonodisperseThermo-ResponsivePNIPAMHollowMicrocapsulesPreparedwithW/OSingleEmulsionsasTemplates……5Thermo-ResponsiveMembranesforChiralResolution6Thermo-ResponsiveMembranesforAf'finitySeparation7pH-ResponsiveGatingMembraneSystemswithPumpingEffects8SmartMicrocapsuleswithpH-ResponsiveHydrogelMembranes9Glucose-ResponsiveGatingMembranes10Molecular-RecognizableSmartMembranes11Dual-/Multi-Stimuli-ResponsiveSmartMembranes12PerspectivesonSmartMembraneMaterialsandSystemsIndex
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