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[美] 卡雷 (Carey.F.A.)、[美] 松德贝里 (Sundberg.R.J.) 著 / 科学出版社 / 2009-01 / 平装
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高等有机化学-结构与机理(第五版)
《高等有机化学:结构与机理(第5版)》自从1997年面世以来,《高等有机化学》作为学科首选教材的地位一直没有动摇过,广泛地覆盖了有机化合物的结构、反应活性及合成。她的第五版相对2001年出版的第四版进行了大幅度的修订,更新了学科发展的相关资料,内容组织更加清晰明朗,特别是计算化学部分。PartA从化合物结构和立体化学基础概念讲起,涉及有机化学反应热力学和动力学的方方面面。主要反应类型涵盖亲核取代反应、加成反应、碳负离子和羰基化学反应、芳环取代反应、周环反应、自由基反应和光化学反应。每章后附有习题精选及解答习题的推荐参考文献。
作者:(美国)卡雷 (Carey.F.A.) (美国)松德贝里 (Sundberg.R.J.)
PrefaceAcknowledgmentandPersonalStatementIntroductionChapter1ChemicalBondingandMolecularStructureIntroduction1.1DescriptionofMolecularStructureUsingValenceBondConcepts1.1.1Hybridization1.1.2TheOriginofElectron-ElectronRepulsion1.1.3ElectronegativityandPolarity1.1.4ElectronegativityEqualization1.1.5DifferentialElectronegativityofCarbonAtoms1.1.6Polarizability,Hardness,andSoftness1.1.7ResonanceandConjugation1.1.8Hyperconjugation1.1.9CovalentandvanderWaalsRadiiofAtoms1.2MolecularOrbitalTheoryandMethods1.2.1TheHiickelMOMethod1.2.2SemiempiricalMOMethods1.2.3AbInitioMethods1.2.4PictorialRepresentationofMOsforMolecules1.2.5QualitativeApplicationofMOTheorytoReactivity:PerturbationalMOTheoryandFrontierOrbitals1.2.6NumericalApplicationofMOTheory1.3ElectronDensityFunctionals1.4RepresentationofElectronDensityDistribution1.4.1MullikenPopulationAnalysis1.4.2NaturalBondOrbitalsandNaturalPopulationAnalysis1.4.3AtomsinMolecules1.4.4ComparisonandInterpretationofAtomicChargeCalculations1.4.5ElectrostaticPotentialSurfaces1.4.6RelationshipsbetweenElectronDensityandBondOrderTopic1.1TheOriginoftheRotational(Torsional)BarrierinEthaneandOtherSmallMoleculesTopic1.2HeteroatomHyperconjugation(AnomericEffect)inAcyclicMoleculesTopic1.3BondinginCyclopropaneandOtherSmallRingCompoundsTopic1.4RepresentationofElectronDensitybytheLaplacianFunctionTopic1.5ApplicationofDensityFunctionalTheorytoChemicalPropertiesandReactivityT1.5.1DFTFormulationofChemicalPotential,Electronegativity,HardnessandSoftness,andCovalentandvanderWaalRadiiT1.5.2DFTFormulationofReactivity——TheFukuiFunction..T1.5.3DFTConceptsofSubstituentGroupsEffectsGeneralReferencesProblemsChapter2Stereoehemistry,Conformation,andStereoselectivity.."Introduction2.1Configuration2.1.1ConfigurationatDoubleBonds2.1.2ConfigurationofCyclicCompounds2.1.3ConfigurationatTetrahedralAtoms2.1.4MoleculeswithMultipleStereogenicCenters2.1.5OtherTypesofStereogenicCenters2.1.6TheRelationshipbetweenChiralityandSymmetry2.1.7ConfigurationatProchiralCenters2.1.8Resolution——TheSeparationofEnantiomers2.2Conformation2.2.1ConformationofAcyclicCompounds2.2.2ConformationsofCyclohexaneDerivatives2.2.3ConformationsofCarbocyclicRingsofOtherSizes2.3MolecularMechanics2.4StereoselectiveandStereospecificReactions2.4.1ExamplesofStereoselectiveReactions2.4.2ExamplesofStereospecificReactions2.5EnantioselectiveReactions2.5.1EnantioselectiveHydrogenation2.5.2EnantioselectiveReductionofKetones2.5.3EnantioselectiveEpoxidationofAllylicAlcohols2.5.4EnantioselectiveDihydroxylationofAlkenes2.6DoubleStereodifferentiation:ReinforcingandCompetingStereoselectivityChapter3StrucralEffectsonStabilityandReactivityChapter4NucleophilicSubstitutionChapter5PolarAdditionandEliminationReactionsChapter6CarbanionsandOtherCarbonNucleophilesChapter7Addition,CondensationandSubstitutionReactionsofCarbonylCompoundsChapter8AromatictityChapter9AromaticSubstitutionChapter10ConcertedPericyclicReactionsChapter11FreeRadicalReactionsChapter12PhotochemistryReferencestoProblemsIndex
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