【目录】 总序i 前言iii 第１部分 化学原理 Part １ Chemical Principles 第1章 气体、液体和溶液的性质3 Chapter 1 The Behaviors of Gas， Liquid and Solution3 1.1 气体的性质3 The Properties of Gases3 1.2 液体17 Liquids17 1.3 溶液23 Solutions23 第2章 化学热力学基础与化学平衡38 Chapter 2 The Basis of Chemical Thermodynamics and Chemical Equilibrium38 2.1 化学热力学的体系与状态38 System and State of Chemical Thermodynamics38 2.2 热力学定律42 First Law of Thermodynamics42 2.3 热化学47 Thermochemistry47 2.4 热力学定律51 Second Law of Thermodynamics51 2.5 化学平衡61 Chemical Equilibrium61 第３章酸碱理论与电离平衡71 Chapter 3 The Theories of Acids & Bases and Ionization Equilibrium71 3.1 酸碱理论71 The Theories of Acids and Bases71 3.2 弱酸弱碱的电离平衡77 The Ionic Equilibrium of Weak Acids and Weak Bases77 3.3 盐的水解89 The Hydrolysis of Salts89 第4章 沉淀反应92 Chapter 4 The Precipitation Reactions92 4.1 溶度积92 Solubility Product92 4.2 沉淀-溶解平衡的移动95 Equilibrium Shift between Precipitation and Dissolution95 4.3 多种沉淀之间的平衡97 Equilibrium in Many Precipitants97 第5章 氧化-还原反应和电化学104 Chapter ５ OxidationReduction Reaction and Electrochemistry104 5.1 氧化-还原反应104 OxidationReduction Reaction104 5.2 电极电势111 Electrode Potential111 5.3 电极电势的应用124 Applications of Electrode Potential124 第６章 化学动力学基础131 Chapter 6 The Basis of Chemical Dynamics131 6.1 化学反应速率131 The Rate of Chemical Reaction131 6.2 化学反应机理154 Reaction Mechanism154 第2部分 化学理论 Ｐart ２ Chemical Theories 第7章 原子结构和元素周期律163 Chapter 7 The Atomic Structure and Periodic System of Elements163 7.1 原子内部的发现164 Discovery of Structure in Atom164 7.2 氢原子光谱和能级的概念170 The Spectrum of Atomic Hydrogen and Concept of Energy Levels170 7.3 原子核外电子的运动状态177 Moving Stations of Electrons outer the Atomic Nucleus177 7.4 多电子原子结构和周期系185 Structure in ManyElectron Atoms and Periodic System185 7.5 元素基本性质的周期性195 Periodic Properties of the Elements195 第8章 化学键和分子、晶体结构202 Chapter 8 Chemical Bonds and Structures of Molecules & Crystals202 8.1 共价键与分子几何构型202 Covalent Bond and Molecular Geometric Structure202 8.2 金属键与金属晶体 232 Metallic Bond and Metallic Crystal232 8.3 离子键与离子晶体243 Ionic Bond and Ionic Crystal243 8.4 晶体学基础257 Basic Crystallology257 第9章 配位化合物267 Chapter 9 The Coordination Compounds267 9.1 配合物的基本概念268 Basic Concepts of Coordination Compounds268 9.2 配位化合物的异构现象279 Isomerism of Coordination Compounds279 9.3 配合物的化学键理论298 The Chemical Bond Theories of Complexes298 9.4 配位平衡及配合物的稳定性315 Coordination Equilibrium and Stabilization of Complex315 9.5 配位化合物的应用322 Application of Coordination Compounds322 第3部分 描述化学 Part3 Descriptive Chemistry s区和p区元素化学引言331 Introduction of the Chemistry of s and p Elements331 第10章 稀有气体334 Chapter 10 The Rare Gases334 10.1 稀有气体的通性 334 General Properties of Rare Gases334 10.2 氙的化学338 Chemistry of Xenon338 第11章 氢、碱金属和碱土金属345 Chapter 11 Hydrogen， Alkali and Alkaliearth Metals345 11.1氢及其化合物345 Hydrogen and Its Compounds345 11.2 碱金属元素及其化合物351 Alkali Metals and Their Compounds351 11.3 碱土金属及其化合物358 Alkaliearth Metals and Their Compounds358 11.4 专题讨论366 Discussion of Special Subjects366 第12章 卤素369 Chapter 12 The Halogens369 12.1 氟及其化合物370 Fluorine and Its Compounds370 12.2 氯及其化合物374 Chlorine and Its Compounds374 12.3 溴分族380 Bromine Subgroup380 12.4 拟卤素和拟卤化物386 Pseudohalogen and Pseudohalide386 第13章 氧族元素390 Chapter 13 The Oxygen Family Elements390 13.1 氧及其化合物391 Oxygen and Its Compounds391 13.2 硫及其化合物398 Sulfur and Its Compounds398 13.3 硒分族407 The Selenium Subgroup407 第14章 氮族元素412 Chapter 14 The Nitrogen Family Elements412 14.1 氮及其化合物413 Nitrogen and Its Compounds413 14.2 磷及其化合物423 Phosphorus and Its Compounds423 14.3 砷分族431 The Arsenic Subgroup431 第15章 碳族元素436 Chapter 15 The Carbon Family Elements436 15.1 碳及其化合物437 Carbon and Its Compounds437 15.2 硅及其化合物445 Silicon and Its Compounds445 15.3 锗分族450 The Germanium Subgroup450 第16章 硼族元素455 Chapter 16 The Boron Family Elements455 16.1 硼及其化合物456 Boron and Its Compounds456 16.2 铝及其化合物466 Aluminum and Its Compounds466 16.3 镓分族470 Gallium Subgroup470 16.4 盐的水解的讨论474 Discussion of Salt Hydrolysis474 第17章 铜、锌分族476 Chapter 17 The Copper Subgroup and Zinc Subgroup476 17.1 铜分族476 The Copper Subgroup476 17.2 锌分族484 The Zinc Subgroup484 第18章 过渡元素（Ⅰ）492 Chapter 18 The Transition Elements（Ⅰ）492 18.1 钛分族495 The Titanium Subgroup495 18.2 钒分族502 The Vanadium Subgroup502 18.3 铬分族507 The Chromium Subgroup507 18.4 锰分族516 The Manganese Subgroup 516 第19章过渡元素（Ⅱ）526 Chapter 19 The Transition Elements（Ⅱ）526 19.1 铁系元素526 The Ferrous Elements526 19.2 铂系元素538 The Platinum Elements538 第20章 镧系元素和锕系元素545 Chapter 20 The Lanthanides and Actinides545 20.1 镧系元素545 The Lanthanides545 20.2 锕系元素560 The Actinites560 Appendix 1 An Element Crossword568 Appendix 2 Thermodynamic Properties of Some Selected Inorganic Compounds572 Appendix 3 Standard HalfCell Reduction Potentials of Selected Elements589 Appendix 4 Charge Densities of Selected Ions593 Appendix 5 Selected Bond Energies596 Appendix 6 Ionization Energies of Selected Metals598 Appendix 7 Electron Affinities of Selected Nonmetals600 Appendix 8 Electronegativities of Selected Elements601 Appendix 9 Selected Lattice Energies602 Appendix 10 Selected Hydration Enthalpies603 Appendix 11 Selected Ionic Radii604 Appendix 12 Vapor Pressure of Water at Various Temperatures605 Appendix 13 Boiling Point Elevation and Freezing Point Depression Constants606 Appendix 14 Enthalpies of Combustion for Some Selected Organic Compounds607 Appendix 15 Dissociation Constants of Weak Acids and Bases608 Appendix 16 Solubility Product Constants of Selected Slightly Electrolytes609 Appendix 17 Formation Constants of Some Selected Complex Ions in Aqueous Solution610 Appendix 18 Physical and Chemical Constants611 元素周期表612 .. .....
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